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Typically when analyzing peptides, polypeptides, or large molecules by ESI (+) MS, the analyte has multiple charges on its structure that are facilitated by the mobile phase additives and ESI source to have a m/z ratio that falls within the detectors range

Nature 464 , 783U163 (2010)

two exceptions to this are in , where in the year 2000 oral vitamin B Canada and Sweden 12 accounted for 73% of the total vitamin B 12 prescribed

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[11] This indicates that animal reproduction studies have shown an adverse effect on the fetus, and there are no adequate, well-controlled studies in pregnant women