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With GSH depleted, IKK becomes constitutively active, driving continuous transcription of TNF-, IL-6, and IL-1

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They promote lipid, protein, and DNA oxidation, forming cytotoxic products such as malondialdehyde (MDA) and 4-hydroxynonenal (4-HNE), which compromise mitochondrial DNA and disrupt electron transport, especially at complexes I and III (Wang et al., 2024)

Simulations for alternative monothiol mechanisms (i) and (ii) from Fig

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