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Finding that interesting loop later led to our understanding of the sensing mechanism, Birsoy says

The band at 1040 cm 1 can be assigned to the S=O stretch vibration and the band around 1739 cm 1 indicates the formation of (C=O) 45,49,50

Mechanisms of glucose sensing in the pancreatic -cell: a computational systems-based analysis

Moreover, the reducing agent acts in a catalytic manner through the formation of an intermediate thioester, as depicted in the mechanism schematized in Figure 3A (see below)